Hello,
Have you imported any raw files into your Skyline document? In your screenshot, I don't see a Raw_file1.skyd file, which is the file that contains chromatograms extracted from the raw data. It's not clear to me what exactly you are trying to accomplish - could you please provide a few more details about what you're trying to do?
If you are new to Skyline, you might find it helpful to start with some of the introductory tutorials here:
https://skyline.ms/wiki/home/software/Skyline/page.view?name=tutorials
Thanks,
Vagisha